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Molecular Multiplicity, M M = 2S + 1 S = spin quantum number of the molecule =... Usually Q is in large molar excess over the excited state and the observed kinetic is a pseudo-first order. Oxygen is an efficient quencher, with quenching rates limited basically by diffusion. At.

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Phosphorus-31 NMR spectroscopy is an analytical chemistry technique that uses nuclear magnetic resonance (NMR) to study chemical compounds that contain phosphorus.Phosphorus is commonly found in organic compounds and coordination complexes (as phosphines), making it useful to measure 31 P NMR spectra routinely. Solution 31 P-NMR is one of the more routine NMR techniques because 31 P has an. Energies for each spin multiplicity directly. The J values can then be determined directly via the Land´e interval rule in Eq. 2. However, due to the multiconﬁgurational nature of the lower spin states, this remains a practical challenge. While multireference methods can... (a conﬁguration with excess on one metal.

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